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Phosphate
Rock Fertiliser: Toxic Metals, Radiation Hazards, Fluoride,
and Organic Growing
George
Glasser - Ros Jones
The NPWA has
a long-standing concern about the phosphate fertiliser industry.
Fluorosilicic acid (H2SiF6), used to fluoridate drinking water,
is derived from the pollution scrubbing operations at those facilities.
We have built up a considerable understanding of phosphate rock
(PR).
The raw rock
(which during phosphate fertiliser production is extensively processed)
is contaminated with heavy metals, radionuclides, other toxic metals
and fluorides. It is recommended for use as an organic fertiliser
in its raw state.
In the process
to make the raw rock into green phosphoric acid, some of the fluorides
are driven off as silicon tetrafluoride gas and a good amount of
the toxic metals/radionuclides are carried away in the gypsum waste
stream. http://www.npwa.freeserve.co.uk/pollution.htm
PR is referred
to in geological terms as fluorapatite. Depending on the region
of the world it comes from, the rock can contain anywhere from 2.0%
to 5.0% fluoride. At five percent, one kilogram contains enough
fluoride to fluoridate 50,000 litres of drinking water.
One ounce @
5.0% fluoride (about the amount used to fertilise one organic tomato
plant as recommended by some organic growers) contains about 1.4
grams of fluoride, which is enough to kill a small child.
Fluoride is
also toxic to many plants (phytotoxic). http://www.ingentaconnect.com/content/jws/jsfa/2003/00000083/00000013/art00012,
http://www.ext.nodak.edu/extpubs/plantsci/landscap/pp744w.htm,
www.publish.csiro.au/?act=view_
file&file_id=SR00036.pdf
Aside from fluorine
pollution, Naturally Occurring Radioactive Materials (NORM) is the
major concern of most government environmental agencies regulating
pollution and phosphorgypsum waste from the manufacture of phosphoric
acid.
Again, depending
on geographic location where the PR is mined, it can contain from
50 - 200 ppm of uranium. PR is the major source of 'yellow cake'
(uranium oxide) for nuclear weapons and the nuclear power industry.
PR is notorious
for its radioactive constituents. The risks it poses are most threatening
to people who come into direct contact with it - eg. organic growers.
However, organic growing organisations seem to be oblivious to these
health hazards - despite the information having been available for
many years.
Where there
is uranium in natural rock formations, there will also be all its
carcinogenic decay rate products; such as radium, radon, radioactive
lead, polonium, thorium, etc.
There are also
toxic metal contaminants such as beryllium, manganese, arsenic,
lead, mercury, cadmium and vanadium.
The tailings
from phosphoric acid production (phosphate fertiliser), phosphorgypsum,
are so radioactive that they are not allowed to be used for wall-board
or road beds in the US and Canada - because it is considered a radiation
hazard. However, organic growers are allowed to treat their fields
with the raw, unprocessed product once every six years, with none
of the contaminants processed out.
http://www.epa.gov/radiation/neshaps/subpartr/more.htm
http://www.efma.org/Publications/BAT%202000/Bat04/section04.asp
Taking a closer
look at this 'natural' PR mix, we find for example polonium-210:
One particle of polonium-210 gives off 5,000 times more alpha radiation
than the same amount of radium. Damage occurs in the body from complete
tissue absorption of the energy of the alpha particle. Polonium-210
can be carcinogenic to people exposed to more than 0.03 microcuries
(6.8 trillionths of a gram). Polonium-210 has a half-life of about
138 days.(There are also high levels of Radium and Polonium- 210
in granite dust, which is used by organic farmers is some parts
of the world as a soil conditioner).
Half Life: Half
of the polonium gives off intense alpha radiation for 138 days until
it turns into regular lead and becomes stable. However, half the
polonium still remains, emitting alpha radiation for another 138
days; then a quarter of the original amount, and so on and so on.
Polonium is
found in tobacco grown with phosphate fertilisers. Studies have
suggested that radioactive polonium may be the primary cause of
smoking-related cancers.
Polonium is
carried throughout the body in the blood. It has been linked to
more soft-tissue cancers than bone cancers; typical sites are the
liver, spleen and kidney.
Radon is also
given off from PR and ground granite. Radon is second only to smoking
as the leading cause of lung cancer in the UK.
Radon is an
important environmental hazard, due to its release of alpha particle
radiation. It has a half life of 3.8 days.
Radon is also
soluble in water. http://www.physics.umaine.edu/radiation/radon.htm
http://energy.cr.usgs.gov/radon/georadon/3.html
http://www.epa.gov/iaq/radon/pubs/physic.html
Radon, in and
of itself, is not a carcinogen. It is the decay products of radon
that are the problem.
If organic growers
are using PR or ground granite, they are being exposed to these
radioactive elements, especially radon. It is important to note
that these do not simply dissipate from the product in a few days,
months or years - these products will emit radon for many thousands
of years.
NPWA would strongly
recommend organic growers to purchase a radon detector/s. PR dust
can be brought into the home on clothes and shoes.
Also, greenhouse
growers should check for radon build-up.
If you use PR
or ground granite for indoor plants, it would be wise to purchase
a radon detector and to re-pot your plants.
NPWA believes
that the promotion of PR and ground granite soil conditioners by
organic growers' organisations endangers the health and well-being
of their members and of people who follow their advice.
NPWA also believes
that the use of raw phosphate rock and ground granite for fertiliser
and/or soil conditioner should be banned for health and safety reasons.
Other reasons
for NPWA opposition to the use of PR are as follows:
1. The use of
phosphate fertilisers is a major contributor to environmental pollution.
2. The act of
mining PR causes ecological devastation in many regions of the world.
http://www.banaban.com/pmining.htm
http://www.waterconserve.info/articles/reader.asp?linkid=42311
http://www.americanrivers.org/site/News2?JServSessionIdr005=qn4zxbzm41.app14a&abbr=AMR _&page=NewsArticle&id=6697&news_iv_ctrl=-1
3. Concern about up-take of fluorides, toxic metals and radionuclides
in produce grown with phosphate fertilisers..
(http://www.medvarsity.com/vmu1.2/dmr/dmrdata/cme/fluorosis/Fluorosis.htm
http://www.floridacenter.org/publications/02_04shiralipour.PDF)
4. The health and wellbeing of growers who have not been informed
about the dangers in using PR.
Further Reference
Material:
http://www.greenpeace.to/publications_pdf/LCC_2002.pdf
http://www.epa.gov/radiation/neshaps/subpartr/more.htm#how_much_radioactivity
http://lqma.ifas.ufl.edu/PUBLICATION-subject.html
http://www.purewatergazette.net/fluorideandphosphate.htm
http://www.epa.gov/radiation/radionuclides/uranium.htm
http://www.bandepleteduranium.org/modules.php?name=Content&pa=showpage&pid=2
http://journals.tubitak.gov.tr/chem/issues/kim-99-23-3/kim-23-3-6-98063.pdf
http://www.uoguelph.ca/~geology/rocks_for_crops/16car.PDF
http://www.webspawner.com/users/radioactivefood/
http://hps.org/publicinformation/ate/q25.html
http://www.ingentaconnect.com/content/iop/jrp/2000/00000020/00000001/art00305
http://www.acsa.net/HealthAlert/RadioFood.html
http://www.ncbi.nlm.nih.gov/entrez/query.fcgi?cmd=Retrieve&db=pubmed&dopt=Abstract&list_uids=11379072&query_hl=2
Phosphates -
http://www.uic.com.au/nip59.htm
Phosphate rock used for fertiliser is a major NORM due to uranium
and thorium. Australian phosphate rock contains up to 900 Bq/kg
and that imported is about twice this, yielding about 1000 Bq/kg
in phosphogypsum waste stream and up to 3000 Bq/kg in the superphosphate
product. In the USA some 50 million tonnes per year are produced
and state figures (UNSCEAR 1977) average up to 10,000 Bq/kg of total
radioactivity. Processing this sometimes gives rise to measurable
doses of radioactivity to people. Phosphate rocks containing up
to 120 ppm U have been used as a source of uranium.
European fertiliser
manufacturing gave rise to discharges of phophogypsum containing
significant quantities of Ra-226, Pb-210 and Po-210 into the North
Sea and North Atlantic. This has been overtaken by offshore oil
and gas production in Norwegian and UK waters releasing some 10
TBq/yr of Ra-226, Ra-228 & Pb-210 - contributing 90% of alpha-active
discharges in those waters (two orders of magnitude more than the
nuclear industry, and with this NORM having higher radiotoxicity).
Also
see: http://www.corpwatch.org/print_article.php?&id=555
http://www.soilandhealth.org/01aglibrary/010134hopkins/010134ch3.html
http://www.epa.gov/radiation/radionuclides/radon.htm
http://web.em.doe.gov/idb97/chap7.html
http://www.geo.tu-freiberg.de/umh/Abstract_View/falck_15_abstract.pdf
http://www.fao.org/documents/show_cdr.asp?url_file=/docrep/007/y5053e/y5053e0d.htm
http://www.schundler.com/florides.htm
http://www1.fipr.state.fl.us/PhosphatePrimer/0/684AE64864D115FE85256F88007AC781
http://www.rdsenvironmental.com/hazmat.radon.html
http://www.soilassociation.org/web/sa/saweb.nsf/0/80256ad8005545498025678d0035fa7d?OpenDocument
http://www.fluoridealert.org/pesticides/Fertilizer.abstracts.1990-.htm
http://static.highbeam.com/a/australianjournalofsoilresearch/may012001
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